Sterically controlled mechanochemistry under hydrostatic pressure

Hao Yan, Fan Yang, Ding Pan, Yu Lin, J. Nathan Hohman, Diego Solis-Ibarra, Fei Hua Li, Jeremy E. P. Dahl, Robert M. K. Carlson, Boryslav A. Tkachenko, Andrey A. Fokin, Peter R. Schreiner, Giulia Galli, Wendy L. Mao, Zhi-Xun Shen and Nicholas A. Melosh ()
Additional contact information
Hao Yan: Stanford Institute for Materials and Energy Sciences
Fan Yang: Stanford Institute for Materials and Energy Sciences
Ding Pan: Hong Kong University of Science and Technology
Yu Lin: Stanford Institute for Materials and Energy Sciences
J. Nathan Hohman: The Molecular Foundry, Lawrence Berkeley National Laboratory
Diego Solis-Ibarra: Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México
Fei Hua Li: Stanford Institute for Materials and Energy Sciences
Jeremy E. P. Dahl: Stanford Institute for Materials and Energy Sciences
Robert M. K. Carlson: Stanford Institute for Materials and Energy Sciences
Boryslav A. Tkachenko: Institute of Organic Chemistry, Justus-Liebig University
Andrey A. Fokin: Institute of Organic Chemistry, Justus-Liebig University
Peter R. Schreiner: Institute of Organic Chemistry, Justus-Liebig University
Giulia Galli: Institute for Molecular Engineering, University of Chicago
Wendy L. Mao: Stanford Institute for Materials and Energy Sciences
Zhi-Xun Shen: Stanford Institute for Materials and Energy Sciences
Nicholas A. Melosh: Stanford Institute for Materials and Energy Sciences

Nature, 2018, vol. 554, issue 7693, 505-510

Abstract: ‘Molecular anvil’ molecules consisting of a compressible mechanophore and incompressible ligands react under hydrostatic pressure to produce elemental metal via an unexplored mechanism.

Date: 2018
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DOI: 10.1038/nature25765

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