Flatband λ-Ti3O5 towards extraordinary solar steam generation

Bo Yang, Zhiming Zhang, Peitao Liu, Xiankai Fu, Jiantao Wang, Yu Cao, Ruolan Tang, Xiran Du, Wanqi Chen, Song Li, Haile Yan, Zongbin Li, Xiang Zhao, Gaowu Qin, Xing-Qiu Chen and Liang Zuo ()
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Bo Yang: Northeastern University
Zhiming Zhang: Northeastern University
Peitao Liu: Chinese Academy of Sciences
Xiankai Fu: Northeastern University
Jiantao Wang: Chinese Academy of Sciences
Yu Cao: Chinese Academy of Sciences
Ruolan Tang: Northeastern University
Xiran Du: Northeastern University
Wanqi Chen: Northeastern University
Song Li: Northeastern University
Haile Yan: Northeastern University
Zongbin Li: Northeastern University
Xiang Zhao: Northeastern University
Gaowu Qin: Northeastern University
Xing-Qiu Chen: Chinese Academy of Sciences
Liang Zuo: Northeastern University

Nature, 2023, vol. 622, issue 7983, 499-506

Abstract: Abstract Solar steam interfacial evaporation represents a promising strategy for seawater desalination and wastewater purification owing to its environmentally friendly character1–3. To improve the solar-to-steam generation, most previous efforts have focused on effectively harvesting solar energy over the full solar spectrum4–7. However, the importance of tuning joint densities of states in enhancing solar absorption of photothermal materials is less emphasized. Here we propose a route to greatly elevate joint densities of states by introducing a flat-band electronic structure. Our study reveals that metallic λ-Ti3O5 powders show a high solar absorptivity of 96.4% due to Ti–Ti dimer-induced flat bands around the Fermi level. By incorporating them into three-dimensional porous hydrogel-based evaporators with a conical cavity, an unprecedentedly high evaporation rate of roughly 6.09 kilograms per square metre per hour is achieved for 3.5 weight percent saline water under 1 sun of irradiation without salt precipitation. Fundamentally, the Ti–Ti dimers and U-shaped groove structure exposed on the λ-Ti3O5 surface facilitate the dissociation of adsorbed water molecules and benefit the interfacial water evaporation in the form of small clusters. The present work highlights the crucial roles of Ti–Ti dimer-induced flat bands in enchaining solar absorption and peculiar U-shaped grooves in promoting water dissociation, offering insights into access to cost-effective solar-to-steam generation.

Date: 2023
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DOI: 10.1038/s41586-023-06509-3

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