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Realization of 2D metals at the ångström thickness limit

Jiaojiao Zhao, Lu Li, Peixuan Li, Liyan Dai, Jingwei Dong, Lanying Zhou, Yizhe Wang, Peihang Zhang, Kunshan Ji, Yangkun Zhang, Hua Yu, Zheng Wei, Jiawei Li, Xiuzhen Li, Zhiheng Huang, Boxin Wang, Jieying Liu, Yutong Chen, Xingchao Zhang, Shuopei Wang, Na Li, Wei Yang, Dongxia Shi, Jinbo Pan, Shixuan Du, Luojun Du () and Guangyu Zhang ()
Additional contact information
Jiaojiao Zhao: Chinese Academy of Sciences
Lu Li: Chinese Academy of Sciences
Peixuan Li: Chinese Academy of Sciences
Liyan Dai: Chinese Academy of Sciences
Jingwei Dong: Chinese Academy of Sciences
Lanying Zhou: Songshan Lake Materials Laboratory
Yizhe Wang: Chinese Academy of Sciences
Peihang Zhang: Chinese Academy of Sciences
Kunshan Ji: Chinese Academy of Sciences
Yangkun Zhang: Chinese Academy of Sciences
Hua Yu: Songshan Lake Materials Laboratory
Zheng Wei: Chinese Academy of Sciences
Jiawei Li: Chinese Academy of Sciences
Xiuzhen Li: Chinese Academy of Sciences
Zhiheng Huang: Chinese Academy of Sciences
Boxin Wang: Chinese Academy of Sciences
Jieying Liu: Songshan Lake Materials Laboratory
Yutong Chen: Songshan Lake Materials Laboratory
Xingchao Zhang: Songshan Lake Materials Laboratory
Shuopei Wang: Songshan Lake Materials Laboratory
Na Li: Songshan Lake Materials Laboratory
Wei Yang: Chinese Academy of Sciences
Dongxia Shi: Chinese Academy of Sciences
Jinbo Pan: Chinese Academy of Sciences
Shixuan Du: Chinese Academy of Sciences
Luojun Du: Chinese Academy of Sciences
Guangyu Zhang: Chinese Academy of Sciences

Nature, 2025, vol. 639, issue 8054, 354-359

Abstract: Abstract Two-dimensional (2D) metals are appealing for many emergent phenomena and have recently attracted research interests1–9. Unlike the widely studied 2D van der Waals (vdW) layered materials, 2D metals are extremely challenging to achieve, because they are thermodynamically unstable1,10. Here we develop a vdW squeezing method to realize diverse 2D metals (including Bi, Ga, In, Sn and Pb) at the ångström thickness limit. The achieved 2D metals are stabilized from a complete encapsulation between two MoS2 monolayers and present non-bonded interfaces, enabling access to their intrinsic properties. Transport and Raman measurements on monolayer Bi show excellent physical properties, for example, new phonon mode, enhanced electrical conductivity, notable field effect and large nonlinear Hall conductivity. Our work establishes an effective route for implementing 2D metals, alloys and other 2D non-vdW materials, potentially outlining a bright vision for a broad portfolio of emerging quantum, electronic and photonic devices.

Date: 2025
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DOI: 10.1038/s41586-025-08711-x

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