Synthesis and Characterization of Novel -Type Zirconium Phosphate-Crystalline Cerium Phosphate/ Polyaniline, Polyindole, Polycarbazole, Polyaniline-co-Polyindole, and Polyaniline-co-Polycarbazole Composites

S. K. Shakshooki, F. A. El-Akari and Najat A. Abozaid
Additional contact information
S. K. Shakshooki: Department of Chemistry, Faculty of Science University of Tripoli, Tripoli, Libya
F. A. El-Akari: Department of Chemistry, Faculty of Science University of Tripoli, Tripoli, Libya
Najat A. Abozaid: Department of Chemistry, Faculty of Science University of Tripoli, Tripoli, Libya

Academic Journal of Chemistry, 2021, vol. 6, issue 2, 45-59

Abstract: -Type zirconium phosphate,-Zr(HPO4)2-.1.77H2O (-ZrP), crystalline cerium phosphate, Ce(HPO4)2.1.33 H2O (CePc), and [-Zr(HPO4)2]0.30 [Ce (HPO4)2]0.70 .2H2O composite were prepared and characterized by chemical, XRD, TGA, FT-IR and scanning electron microscopy(SEM). [-Zr(HPO4)2]0.30[Ce(HPO4)2]0.70/polyaniline, polyindole, polycarbazole, polyaniline-co-polyindole, polyaniline-co-polycarbazole composites were prepared via in-situ chemical oxidation of the monomers aniline, indole , carbazole, and (1:1moler ratio) of co-monomers aniline-indole, aniline- carbazole, respectively, that was promoted by the reduction of part of Ce(IV) ions present in the inorganic matrix. A possible explanation is part of CePc is attacked by the monomers, and the co-monomers, respectively, converted to cerium (III) orthophosphate (CePO4). The resultant novel composites were characterized by elemental (C,H,N) analysis, FT-IR, and (SEM). From elemental (C,H,N) analysis ,the amount of organic materials present in [-Zr(HPO4)2]0.30 [Ce (HPO4)2]0.70/ polyaniline, polyindole, polycarbazole composites were (23.44, 5.24 and  33.02 % in wt. ), respectively. The amount of resultant copolymers were (Pani 5.92, PIn 7.48 % in wt) and (Pani 1.42, PCz 2.48 % in wt ) These composites can be considered as novel conducting inorganic-organic composites, ion exchangers , solid acid catalysts and sensors.

Keywords: T-type zirconium phosphate; Crystalline cerium phosphate; Polyaniline; Polyindole; Polycarbazole and their copolymers composites. (search for similar items in EconPapers)
Date: 2021
References: View complete reference list from CitEc
Citations:

Downloads: (external link)
https://www.arpgweb.com/pdf-files/ajc6(2)45-59.pdf (application/pdf)
https://www.arpgweb.com/journal/20/archive/06-2021/2/6 (text/html)

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:arp:ajcarp:2021:p:45-59

DOI: 10.32861/ajc.62.45.59

Access Statistics for this article

Academic Journal of Chemistry is currently edited by Prof. Dr. Sadek khalifa Shakshooki

More articles in Academic Journal of Chemistry from Academic Research Publishing Group Rahim Yar Khan 64200, Punjab, Pakistan.
Bibliographic data for series maintained by Managing Editor ().