A real-time distributed solid oxide electrolysis cell (SOEC) model for cyber-physical simulation

Biao Zhang, Nor Farida Harun, Nana Zhou, Danylo Oryshchyn, Jose J. Colon-Rodriguez, Lawrence Shadle, Samuel Bayham and David Tucker

Applied Energy, 2025, vol. 388, issue C, No S030626192500337X

Abstract: System integration and dynamic operability between SOEC and balance-of-plant (BoP) components are major technical challenges before realizing rapid load following of SOEC systems. Cyber-physical simulation (CPS) is a leading-edge digital engineering approach and is regarded as the next step beyond Digital Twins. CPS approach can be used to research SOEC system integration and develop dynamic controls prior to actual pilot testing without using a real SOEC. To seamlessly couple with BoP hardware and access non-observable operational parameters (e.g., local temperature gradient) during transients, a distributed one-dimensional (1D) real-time SOEC model was developed. Its real-time execution was demonstrated for 20 to 640 nodes at the fixed time step of 5 ms. A higher excess air ratio enabled smaller local temperature gradients on SOEC solid materials and faster transients upon current density step change from 0.15 to 0.55 A cm−2. During the transients, the magnitude of the peak temperature gradient nearly doubled in 10 s from −3.5 to −5.9 °C cm−1. This represents a significant operating risk that can impact the dynamic operability of SOEC systems. In addition, the local temperature gradient was found to change directions on all nodes in SOEC solid materials, with the greatest impact on the upstream nodes. The SOEC model was also tested at the thermal neutral voltage using actual process air flow parameters as variable model inputs. Variable process air temperatures were found to induce alternating local temperature gradients on SOEC solid materials. These are new operational mechanisms for SOEC degradation relevant for load following operational modes yet distinct from previous reports. To mitigate these unfavorable features, the SOEC can be operated at voltages that are slightly (±20 mV) deviated from the thermal neutral voltage. The corresponding net thermal energy change was less than 1.6% of the electric power consumption. This 1D real-time SOEC model established the basis of cyber-physical simulation of SOEC hybrid systems.

Keywords: Solid oxide electrolysis cell; Cyber-physical simulation; Temperature gradient; Dynamic operability; Real-time simulation (search for similar items in EconPapers)
Date: 2025
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DOI: 10.1016/j.apenergy.2025.125607

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