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Comparison of the effect of linear and two-step fast charging protocols on degradation of lithium ion batteries

Meng Xu, Xia Wang, Liwen Zhang and Peng Zhao

Energy, 2021, vol. 227, issue C

Abstract: This work compares the effect of linear and two-step fast charging protocols on degradation of the Li-ion battery due to the solid electrolyte interphase (SEI) increase with the charging-discharging cycles based on an electrochemical and capacity fade coupled cell model. Since there is still a lack of knowledge regarding how the State of Charge (SOC) – dependent charging profile affects battery degradation, different slopes of the linear charging profile and different combinations of the charging current level for the two-step charging protocol are chosen as sample protocols representing the profiles varying with the SOC. The simulation results indicate that the two-step increasing charging protocol can achieve the lowest capacity fade ratio over 3000 cycles; the linear decreasing charging protocol can achieve the lowest charging voltage increase. The capacity fade due to the SEI layer increase in the negative electrode results in a shift of the stoichiometry coefficient cycling range and therefore a lower cell equilibrium potential and power performance.

Keywords: Fast charging protocol; Charging current profile; Capacity fade model; Electrochemical model; Degradation; SEI increase (search for similar items in EconPapers)
Date: 2021
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (4)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:227:y:2021:i:c:s0360544221006666

DOI: 10.1016/j.energy.2021.120417

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